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RSIGuard Stretch Edition - RSIGuard is an ergonomic tool for the prevention of Repetitive Strain Injuries (e.g. carpal tunnel, deQuervain's, tendinitis etc.) including trauma modeling break timer, automatic mouse-clicking, macros & automatic long-term work pattern logging.

SayPad - SayPad, the freeware talking text editor can read you a good book or help you write one, using SAPI 5.1 Text To Speech (included). It can convert Text to MP3 for a whole book in one run, splitting off chapters into well named MP3 files.

Sayz Me - Sayz Me is a text-to-speech application. Text can be typed in or read from clipboard. Words are highlighted when spoken. Select voice, adjust reading speed, voice pitch, font and color. Hides in system tray. Simple and easy to use. Freeware.

Sheer Notes - Sheer yellow notes on your desktop. Great for to-do lists, reminders, and for processing text. Notes windows are fully resizable, and can be made semi-transparent, so they can be visible all the time, while still being relatively innocuous.

Sogol - Math Assistant and Hypertext Notepad for Engineers and Scientists using Windows. Assists with calculating networks of formulae, dynamic simulations, equation solutions, differential, multiple equations and unknowns, with built-in script language.